docs: restructure knowledge base into tree layout + gA extraction module

- Organize into tree structure: corrections/, nuclear-structure/, gA-extraction/, refs/
- Move all correction notes to corrections/ (01-09)
- Move nuclear structure to nuclear-structure/ with index
- Add gA-extraction/ with SSM algorithm, sNME/ESSM formalism, Tc99 case study, and implementation TODO
- Reorganize refs by topic (electromagnetic/, forbidden-decay/)
- Update all wikilinks to new paths
- Remove radiative_spec.md (code algorithm, not reference)
- Lint: all wikilinks verified valid
- Comprehensive gA extraction research based on Paulsen et al. (2024) and Song et al. (2025)
This commit is contained in:
2026-05-14 19:46:39 +03:00
parent efcd6a524a
commit 030ae3e4b9
29 changed files with 696 additions and 771 deletions
+88
View File
@@ -0,0 +1,88 @@
---
title: "05 – Exchange Correction"
date: 2026-04-26
tags:
- beta-spectrum/correction/exchange
status: active
aliases: [Atomic Exchange, X(Z,W), Hayen-2018]
cssclasses: []
related_components: [[corrections/03-screening]], [[corrections/08-atomic-overlap]]
---
# Atomic Electron Exchange Correction $X(Z,W)$
## Physical Origin
When a β electron is emitted from the nucleus, it can exchange with bound atomic electrons due to indistinguishability (Pauli exclusion principle). This **electron exchange** effect modifies the β spectrum at low energies where the continuum electron's wave function overlaps significantly with atomic orbitals.
> [!key] Magnitude
> The exchange contribution can exceed **20% in low-energy regions for higher Z** nuclei — it is one of the largest atomic corrections and absolutely critical for precision work below ~10 keV.
## Theory: Full Potential Approach
Exchange requires radial wave functions of both continuum and bound states integrated over **all space** (not just near origin). This is computationally demanding for analytical description because:
- Exchange needs integration over entire spatial domain
- Hydrogenic approach with simple screening is insufficient for high precision
- Must use realistic atomic potentials (Dirac-Hartree-Fock-Slater)
### Three Potential Models Compared (Hayen Fig. 9)
| Model | Description | Accuracy |
|---|---|---|
| **Unoptimized** | Basic Hartree-Fock-Slater, no exchange optimization | Lower bound |
| **Salvat** | Parametrized atomic potential | Intermediate |
| **Optimized** | Full potential with exchange optimization included | Target ($10^{-4}$) |
Screening strength is adjusted for best agreement with bound state energies (decreasing importance for higher $n$).
## Analytical Parametrisation — Hayen et al. 2018
The exchange correction $X(W)$ as a function of kinetic energy uses empirical fit coefficients from Table X of [[refs/electromagnetic/2017_Hayen_analytical_beta_shape/summary]]. Coefficients are tabulated for all atoms with $Z = 2$ through $z = 120$.
### Shell Structure Effects
> [!tip] Figure 9 observation
> Clear shell closure effects observed in orbital exchange contributions: at noble gas Z values, the exchange correction shows characteristic kinks. These must be captured by interpolation between tabulated Z values.
## Calculator Implementation
> [!tip] Code mapping
> Module: `beta_spectrum/components/exchange.py` → `ExchangeCorrection(Z)` class
>
> Loads empirical fit coefficients from `data/exchange_coeff.csv` (119 rows, $Z = 2$–$120$). Uses interpolation between tabulated values.
### Data File
```
beta_spectrum/data/exchange_coeff.csv
├── Row count: 119 (Z=2 to Z=120)
├── Columns: Z, fit coefficients a₀...aₙ for energy parametrisation
└── Source: Hayen et al., Phys. Rev. D 97, 013006 (2018), Table X
```
### API Usage
```python
from beta_spectrum import ExchangeCorrection
exch = ExchangeCorrection(Z=90) # Z of parent atom
values = exch(W_grid) # returns correction factor at each W
```
## Energy Dependence
- **Dominant at very low energies** (T < ~10 keV): where continuum electron overlaps with atomic orbitals
- Decreases rapidly above ~50 keV (continuum wave function too short-ranged for significant overlap)
- For medium/high Z nuclei, shake-off probability in $s_{1/2}$ or $p_{1/2}$ state is < 0.1% — negligible
## Shake-Up Influence on Exchange
In low-Z nuclei (e.g., tritium):
- Shake-up probabilities can be significant (~25%)
- Exchange with higher-lying ns orbitals must be included even if unoccupied in initial state
For most practical cases, inclusion of shake-up changes the exchange correction at the few $10^{-4}$ level down to 0.5 keV for tritium only — otherwise negligible.
## Code Status: ✓ Implemented
The `ExchangeCorrection` class is fully implemented and tested. The CSV data file covers the full range from light (He, Z=2) to transuranic (U, Z=92+) elements.